Defects on the Surface of Ti-Doped MgAl2O4 Nanophosphor
نویسندگان
چکیده
Ti-doped nano MgAl2O4 for white emission was synthesized by combustion method. Extrinsic Schottky defects, Al vacancies and Ti4+ dopant in Al sites, which are considered to be responsible for bluish-white emission, were observed by STEM on the surface of Ti-doped nano MgAl2O4 powder. The stabilities of the Schottky defect associates, (TiAl·-VAl''')'', were demonstrated by DFT calculation. The emission behavior was interpreted with these results.
منابع مشابه
Spectroscopic studies of Ti3+ ions speciation inside MgAl2O4 spinels
An electron paramagnetic resonance (EPR) investigation on Ti-doped MgAl2O4 spinels has been made in order to study the Ti sites. The study we present here concerns the angular dependencies of the Ti EPR lines and the variations of the EPR spectra due to a modification of the TiO2 content or of the chemical composition from MgAl2O4 to MgAl4O7 and MgAl6O10. In all the studied samples except one, ...
متن کاملThe Effect of Annealing, Synthesis Temperature and Structure on Photoluminescence Properties of Eu-Doped ZnO Nanorods
In this study un-doped and Eu-doped ZnO nanorods and microrads were fabricated by Chemical Vapor Deposition (CVD) method. The effects of annealing, synthesis temperature and structure on structural and photoluminescence properties of Eu-doped ZnO samples were studied in detail. Prepared samples were characterized using X-Ray diffraction (XRD), scanning electron microscopy (SEM), particle size a...
متن کاملDevelopment of Al-Ti-N Composite Coatings on Commercially Pure Ti Surface by Tungsten Inert Gas Process
The present work aims to modify surface properties of pure Ti by development of Ti-Al-N intermetallic composite coatings. In this regard, tungsten inert gas (TIG) cladding process was carried out using Al 1100 as filler rod with Ar and Ar+N2 as shielding gases. Phase and structure of the samples were investigated by X-ray diffraction (XRD) technique, optical microscopy (OM) and scanning electro...
متن کاملSYNTHESIS OF MgAl2O4-Ti(C,N) NANOCOMPOSITE BY ALUMINOTHERMIC REDUCTION
MgAl2O4/Ti(C,N) composites were synthesized through aluminothermic reaction between Al,TiO 2,MgO powders and phenolic resin in coke bed condition. Effect of addition of carbon black and sugar into the mixture at different temperatures were investigated. The phases and microstructures of samples were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). MgAl 2O4 ...
متن کاملIon-Doped Silicate Bioceramic Coating of Ti-Based Implant
Titanium and its alloy are known as important load-bearing biomaterials. The major drawbacks of these metals are fibrous formation and low corrosion rate after implantation. The surface modification of biomedical implants through various methods such as plasma spray improves their osseointegration and clinical lifetime. Different materials have been already used as coatings on biomedical implan...
متن کامل